638 research outputs found
Modeling electrodialysis and a photochemical process for their integration in saline wastewater treatment.
Oxidation processes can be used to treat industrial wastewater containing non-biodegradable organic compounds. However, the presence of dissolved salts may inhibit or retard the treatment process. In this study, wastewater desalination by electrodialysis (ED) associated with an advanced oxidation process (photo-Fenton) was applied to an aqueous NaCl solution containing phenol. The influence of process variables on the demineralization factor was investigated for ED in pilot scale and a correlation was obtained between the phenol, salt and water fluxes with the driving force. The oxidation process was investigated in a laboratory batch reactor and a model based on artificial neural networks was developed by fitting the experimental data describing the reaction rate as a function of the input variables. With the experimental parameters of both processes, a dynamic model was developed for ED and a continuous model, using a plug flow reactor approach, for the oxidation process. Finally, the hybrid model simulation could validate different scenarios of the integrated system and can be used for process optimization
Seeding Strategies for Multi-Objective Test Case Selection: An Application on Simulation-based Testing
The time it takes software systems to be tested is usually long. This is often caused by the time it takes the entire test suite to be executed. To optimize this, regression test selection approaches have allowed for improvements to the cost-effectiveness of verification and validation activities in the software industry. In this area, multi-objective algorithms have played a key role in selecting the appropriate subset of test cases from the entire test suite. In this paper, we propose a set of seeding strategies for the test case selection problem that generate the initial population of multi-objective algorithms.We integrated these seeding strategies with an NSGA-II algorithm for solving the test case selection problem in the context of simulation-based testing. We evaluated the strategies with six case studies and a total of 21 fitness combinations for each case study (i.e., a total of 126 problems). Our evaluation suggests that these strategies are indeed helpful for solving the multi-objective test case selection problem. In fact, two of the proposed seeding strategies outperformed the NSGA-II algorithm without seeding population with statistical significance for 92.8 and 96% of the problems
Evolution of local recruitment and its consequences for marine populations
Advantages of dispersal on the scales that are possible in a long pelagic larval period are not apparent, even for benthic species. An alternative hypothesis is that wide dispersal may be an incidental byproduct of an ontogenetic migration from and then back to the parental habitat. Under this hypothesis, the water column is a better habitat than the bottom for early development. Because the parental area is often an especially favorable habitat for juveniles and adults, selection may even favor larval retention or larval return rather than dispersal. Where larval capabilities and currents permit, a high percentage of recruits may then be produced from local adults. Expected consequences of a high proportion of local recruitment are stronger links between stock and recruitment, greater vulnerability to recruitment overfishing and local modifications of habitat, greater local benefits from fishery reserves, and possibly more localized adaptation within populations. Export of some larvae is consistent with a high proportion of retained or returning larvae, could stabilize populations linked by larval exchange, and provide connectivity between marine reserves. Even a small amount of larval export could account for the greater gene flow, large ranges, and long evolutionary durations seen in species with long pelagic larval stages
Probing structural relaxation in complex fluids by critical fluctuations
Complex fluids, such as polymer solutions and blends, colloids and gels, are
of growing interest in fundamental and applied soft-condensed-matter science. A
common feature of all such systems is the presence of a mesoscopic structural
length scale intermediate between atomic and macroscopic scales. This
mesoscopic structure of complex fluids is often fragile and sensitive to
external perturbations. Complex fluids are frequently viscoelastic (showing a
combination of viscous and elastic behaviour) with their dynamic response
depending on the time and length scales. Recently, non-invasive methods to
infer the rheological response of complex fluids have gained popularity through
the technique of microrheology, where the diffusion of probe spheres in a
viscoelastic fluid is monitored with the aid of light scattering or microscopy.
Here we propose an alternative to traditional microrheology that does not
require doping of probe particles in the fluid (which can sometimes drastically
alter the molecular environment). Instead, our proposed method makes use of the
phenomenon of "avoided crossing" between modes associated with the structural
relaxation and critical fluctuations that are spontaneously generated in the
system.Comment: 4 pages, 4 figure
Conformational Mechanics of Polymer Adsorption Transitions at Attractive Substrates
Conformational phases of a semiflexible off-lattice homopolymer model near an
attractive substrate are investigated by means of multicanonical computer
simulations. In our polymer-substrate model, nonbonded pairs of monomers as
well as monomers and the substrate interact via attractive van der Waals
forces. To characterize conformational phases of this hybrid system, we analyze
thermal fluctuations of energetic and structural quantities, as well as
adequate docking parameters. Introducing a solvent parameter related to the
strength of the surface attraction, we construct and discuss the
solubility-temperature phase diagram. Apart from the main phases of adsorbed
and desorbed conformations, we identify several other phase transitions such as
the freezing transition between energy-dominated crystalline low-temperature
structures and globular entropy-dominated conformations.Comment: 13 pages, 15 figure
Josephson tunneling in high- superconductors
This article describes the Josephson tunneling from time-reversal
symmetry-breaking states and compares it with that from time-reversal invariant
states for both twinned and untwinned crystals and for both -axis and
basal-plane currents, in a model for orthorhombic YBCO. A macroscopic
invariance group describing the superconducting state of a twinned crystal is
introduced and shown to provide a useful framework for the discussion of the
results for twinned crystals. In addition, a ring geometry, which allows
-wave and -wave superconductivity in a tetragonal
superconductor to be distinguished on the basis of symmetry arguments only, is
proposed and analyzed. Finally, an appendix gives details of the experimental
Josephson tunneling evidence for a superconducting state of orthorhombic
symmetry in YBCO.Comment: Latex File, 18 pages, 6 Postscript figures, submitted to Phys. Rev.
Scale-free static and dynamical correlations in melts of monodisperse and Flory-distributed homopolymers: A review of recent bond-fluctuation model studies
It has been assumed until very recently that all long-range correlations are
screened in three-dimensional melts of linear homopolymers on distances beyond
the correlation length characterizing the decay of the density
fluctuations. Summarizing simulation results obtained by means of a variant of
the bond-fluctuation model with finite monomer excluded volume interactions and
topology violating local and global Monte Carlo moves, we show that due to an
interplay of the chain connectivity and the incompressibility constraint, both
static and dynamical correlations arise on distances . These
correlations are scale-free and, surprisingly, do not depend explicitly on the
compressibility of the solution. Both monodisperse and (essentially)
Flory-distributed equilibrium polymers are considered.Comment: 60 pages, 49 figure
Transcriptome Analysis and SNP Development Can Resolve Population Differentiation of Streblospio benedicti, a Developmentally Dimorphic Marine Annelid
Next-generation sequencing technology is now frequently being used to develop genomic tools for non-model organisms, which are generally important for advancing studies of evolutionary ecology. One such species, the marine annelid Streblospio benedicti, is an ideal system to study the evolutionary consequences of larval life history mode because the species displays a rare offspring dimorphism termed poecilogony, where females can produce either many small offspring or a few large ones. To further develop S. benedicti as a model system for studies of life history evolution, we apply 454 sequencing to characterize the transcriptome for embryos, larvae, and juveniles of this species, for which no genomic resources are currently available. Here we performed a de novo alignment of 336,715 reads generated by a quarter GS-FLX (Roche 454) run, which produced 7,222 contigs. We developed a novel approach for evaluating the site frequency spectrum across the transcriptome to identify potential signatures of selection. We also developed 84 novel single nucleotide polymorphism (SNP) markers for this species that are used to distinguish coastal populations of S. benedicti. We validated the SNPs by genotyping individuals of different developmental modes using the BeadXPress Golden Gate assay (Illumina). This allowed us to evaluate markers that may be associated with life-history mode
Recruitment in the sea: bacterial genes required for inducing larval settlement in a polychaete worm
Metamorphically competent larvae of the marine tubeworm Hydroides elegans can be induced to metamorphose by biofilms of the bacterium Pseudoalteromonas luteoviolacea strain HI1. Mutational analysis was used to identify four genes that are necessary for metamorphic induction and encode functions that may be related to cell adhesion and bacterial secretion systems. No major differences in biofilm characteristics, such as biofilm cell density, thickness, biomass and EPS biomass, were seen between biofilms composed of P. luteoviolacea (HI1) and mutants lacking one of the four genes. The analysis indicates that factors other than those relating to physical characteristics of biofilms are critical to the inductive capacity of P. luteoviolacea (HI1), and that essential inductive molecular components are missing in the non-inductive deletion-mutant strains
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